Synthesis of latex particles by ring-opening metathesis polymerization

被引:23
作者
Quémener, D [1 ]
Chemtob, A [1 ]
Héroguez, V [1 ]
Gnanou, Y [1 ]
机构
[1] Univ Bordeaux 1, ENSCPB, UMR CNRS, Lab Chim Polymeres Org, F-33607 Pessac, France
关键词
ring-opening metathesis polymerization; dispersion polymerization; suspension polymerization;
D O I
10.1016/j.polymer.2004.11.096
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This paper reviews the recent discoveries that were achieved by our group in the field of particle synthesis via ring-opening metathesis polymerization (ROMP). Both polynorbornene and polybutadiene-based particles were prepared by the respective ROMP of norbornene and cyclooctadiene initiated by (PCY3)(2)Cl2Ru=CHPh using several methods of polymerization in dispersed media, such as dispersion, suspension and miniemulsion. Depending upon the process implemented, particles size was found to range from 300 nm to 20 mum. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1067 / 1075
页数:9
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