On-Site Determination of Carbendazim, Cathecol and Hydroquinone in Tap Water Using a Homemade Batch Injection Analysis Cell for Screen Printed Electrodes

被引:20
作者
Caramit, Ricardo Pini [1 ]
Lucca, Bruno Gabriel [1 ]
Ferreira, Valdir Souza [1 ]
Abarza Munoz, Rodrigo Alejandro [2 ]
Richter, Eduardo Mathias [2 ]
Bezerra da Silva, Rodrigo Amorim [3 ]
机构
[1] Univ Fed Mato Grosso do Sul, Inst Quim, BR-79074460 Campo Grande, MS, Brazil
[2] Univ Fed Uberlandia, Inst Quim, BR-38408100 Uberlandia, MG, Brazil
[3] Fundacao Univ Fed Grande Dourados, Fac Ciencias Exactas & Tecnol, BR-79804970 Dourados, MS, Brazil
关键词
Batch injection analysis (BIA); Screen-printed electrodes; Homemade portable system; On-site analysis; STRIPPING VOLTAMMETRY; CONTINUOUS-FLOW; NATURAL-WATERS; FIELD ANALYSIS; SYSTEM; CARBON; BIODIESEL; ANALYZER;
D O I
10.1002/elan.201400454
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this work, we present a simple homemade batch-injection analysis cell for screen-printed electrodes (BIA-SPE). The potential of the proposed system for on-site analysis was demonstrated by the determination of carbendazim, catechol, and hydroquinone in tap water. The system provided reduced injection volume (30 mu L), high analytical frequency (approximate to 200 h(-1)) and low detection limits (nanomolar level). Moreover, the BIA-SPE cell presented better stability (RSD approximate to 0.4%) than a conventional flow injection cell for SPE (RSD approximate to 5.0%) in organic media. The proposed homemade BIA-SPE cell is very simple, inexpensive and can be easily constructed in any laboratory.
引用
收藏
页码:271 / 275
页数:5
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