Thermodynamics of polar fluid mixtures of hard non-spherical molecules

被引:0
|
作者
Singh, SP [1 ]
Sinha, SK [1 ]
机构
[1] BBA Bihar Univ, LS Coll, Dept Phys, Muzaffarpur 842001, Bihar, India
来源
INDIAN JOURNAL OF PHYSICS AND PROCEEDINGS OF THE INDIAN ASSOCIATION FOR THE CULTIVATION OF SCIENCE-PART B | 2003年 / 77B卷 / 04期
关键词
polar fluid mixture; virial coefficients; equations of state;
D O I
暂无
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The,problem of calculating the thermodynamic properties of polar fluid mixtures of hard non-spherical molecules is studied. Explicit analytic expressions for the virial coefficients and Helmholz free energy are given. Numerical results are estimated for the third virial coefficient, equation of state and excess internal energy of quadrupolar hard gaussian overlap fluid mixtures. They are found to depend on the conditions and shape parameters.
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页码:457 / 463
页数:7
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