Amino acids as biomimetic crystallization agents for the synthesis of ZIF-8 particles

被引：62

作者：

Liang, Kang ^{[1
]}

Ricco, Raffaele ^{[1
]}

Doherty, Cara M. ^{[1
]}

Styles, Mark J. ^{[1
]}

Falcaro, Paolo ^{[1
,2
]}

机构：

[1] CSIRO Mfg Flagship, Private Bag 10, Clayton, Vic 3169, Australia

[2] Graz Univ Technol, Inst Phys & Theoret Chem, Stremayrgasse 9, A-8010 Graz, Austria

来源：

CRYSTENGCOMM | 2016年 / 18卷 / 23期

基金：

澳大利亚研究理事会;

关键词：

METAL-ORGANIC FRAMEWORKS; ZEOLITIC IMIDAZOLATE FRAMEWORKS; AQUEOUS-SOLUTION; NANOCRYSTALS; NANOSPHERES; SEPARATION; STABILITY; MEMBRANES;

D O I：

10.1039/c5ce02549d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Biomimetic mineralization of metal-organic frameworks (MOFs) exploits the use of biomolecules to control MOF crystallization processes. Here, we investigate 20 natural amino acids as biomimetic crystallization agents for the synthesis of ZIF-8 particles in aqueous solution. The morphology, size, and particle number of resultant MOF crystals were strongly dependent on the chemical nature of amino acid side chains that match closely the four classes of amino acids: nonpolar, polar neutral, polar negative and polar positive.

引用

页码：4264 / 4267

页数：4

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