Asymmetric methoxyselenenylation of alkyl vinyl ethers: a new route to chiral acetals

被引：20

作者：

Uchiyama, M ^{[1
]}

Satoh, S ^{[1
]}

Ohta, A ^{[1
]}

机构：

[1] Tokyo Univ Pharm & Life Sci, Sch Pharm, Tokyo 1920392, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 08期

关键词：

chiral selenium compounds; asymmetric methoxyselenenylation; vinyl ethers; chiral acetals;

D O I：

10.1016/S0040-4039(00)02285-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The asymmetric methoxyselenenylation of alkyl vinyl ethers afforded the corresponding chiral acetals with moderate to good diastereoselectivity. This reaction and subsequent deselenenylation provided a new method of preparing enantiomerically enriched acetals in which the acetal carbon was the only stereogenic center. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1559 / 1562

页数：4