Effect of the mineral matrix in the reactions of oil shales: 1. Pyrolysis reactions of Turkish Goynuk and US Green River oil shales

被引：96
|
作者：
Karabakan, A [1 ]
Yurum, Y [1 ]
机构：
[1] Hacettepe Univ, Dept Chem, TR-06532 Ankara, Turkey
来源：
FUEL | 1998年 / 77卷 / 12期
关键词：
oil shale; pyrolysis; minerals; kerogen;
D O I：
10.1016/S0016-2361(98)00045-3
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The effect of the mineral matrix of Turkish Goynuk and Green River oil shales on the conversion of kerogen into organic material in pyrolysis reactions was investigated in this study. The conversion of kerogen to volatile organic material in pyrolysis reactions increased with increased reaction temperatures for the original and demineralized products of oil shales. Increasing the heating rate also caused greater kerogen conversion. It was found that pyrolysis reactions were catalyzed by alkaline earth metal cations in carbonates and inhibited by silicates. The inhibition effect of the silicates seemed to be greater than the catalytic effect of the carbonates in the pyrolysis reactions of the original Goynuk and Green River oil shales. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1303 / 1309
页数：7
相关论文
共 21 条
  • [1] Effect of the mineral matrix in the reactions of shales.: Part 2.: Oxidation reactions of Turkish Goynuk and US Western Reference oil shales
    Karabakan, A
    Yürüm, Y
    FUEL, 2000, 79 (07) : 785 - 792
  • [2] MINERAL REACTIONS IN THE PROCESSING OF AUSTRALIAN TERTIARY OIL SHALES
    PATTERSON, JH
    HURST, HJ
    LEVY, JH
    KILLINGLEY, JS
    FUEL, 1990, 69 (09) : 1119 - 1123
  • [3] EFFECT OF LIGNITE ADDITION AND STEAM ON THE PYROLYSIS OF TURKISH OIL SHALES
    EKINCI, E
    CITIROGLU, M
    PUTUN, E
    LOVE, GD
    LAFFERTY, CJ
    SNAPE, CE
    FUEL, 1992, 71 (12) : 1511 - 1514
  • [4] EFFECT OF MINERAL MATTER ON PRODUCT YIELD AND COMPOSITION AT ISOTHERMAL PYROLYSIS OF TURKISH OIL SHALES
    Sert, M.
    Ballice, L.
    Yuksel, M.
    Saglam, M.
    OIL SHALE, 2009, 26 (04) : 463 - 474
  • [5] Evolution of volatile products from Goynuk (Turkey) oil shales by temperature-programmed pyrolysis
    Ballice, L
    Yuksel, M
    Saglam, M
    Schulz, H
    FUEL, 1997, 76 (05) : 375 - 380
  • [6] Non-isothermal pyrolysis kinetics of three Turkish oil shales
    Dogan, OM
    Uysal, BZ
    FUEL, 1996, 75 (12) : 1424 - 1428
  • [7] Smoldering Combustion in Oil Shales: Influence of Calcination and Pyrolytic Reactions
    Elayeb, Mustafa
    Debenest, Gerald
    Mourzenko, Valeri V.
    Thovert, Jean-Francois
    TRANSPORT IN POROUS MEDIA, 2017, 116 (02) : 889 - 921
  • [8] Smoldering Combustion in Oil Shales: Influence of Calcination and Pyrolytic Reactions
    Mustafa Elayeb
    Gérald Debenest
    Valeri V. Mourzenko
    Jean-François Thovert
    Transport in Porous Media, 2017, 116 : 889 - 921
  • [9] Effect of demineralization and heating rate on the pyrolysis kinetics of Jordanian oil shales
    Al-Harahsheh, Mohammad
    Al-Ayed, Omar
    Robinson, John
    Kingman, Sam
    Al-Harahsheh, Adnan
    Tarawneh, Khalid
    Saeid, Abdurrahman
    Barranco, Richelieu
    FUEL PROCESSING TECHNOLOGY, 2011, 92 (09) : 1805 - 1811
  • [10] EFFECT OF ORGANIC MATTER CONTENT AND TYPE OF MINERAL MATTER ON THE OIL YIELD FROM OIL SHALES
    Johannes, Ille
    Luik, Hans
    Bojesen-Koefoed, Jorgen A.
    Tiikma, Laine
    Vink, Natalia
    Luik, Lea
    OIL SHALE, 2012, 29 (03) : 206 - 221
123