Free-Radical copolymerization of N-vinylsuccinimide with butyl acrylate in the presence of zinc chloride and aluminum chloride

被引：0

作者：

Sivtsov, E. V. ^{[1
]}

Gostev, A. I. ^{[1
]}

机构：

[1] St Petersburg State Technol Inst Tech Univ, St Petersburg 190013, Russia

来源：

POLYMER SCIENCE SERIES B | 2010年 / 52卷 / 7-8期

关键词：

Copolymerization; Polymer Science Series; Benzyl Alcohol; Aluminum Chloride; Butyl Acrylate;

D O I：

10.1134/S1560090410070110

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The free-radical copolymerization of N-vinylsuccinimide with butyl acrylate performed in dimethyl sulfoxide and benzyl alcohol in the presence of zinc chloride and aluminum chloride as complexing agents is studied. Under the given conditions, the reactivity ratios are determined. It is shown that zinc chloride influences the electron-density distribution only in butyl acrylate molecules. It is found that benzyl alcohol retards the total rate of polymerization. The character of the monomer-unit distribution in copolymer macromolecules is described.

引用

页码：465 / 472

页数：8

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