Multifunctional Charge-Transfer Single Crystals through Supramolecular Assembly

被引:26
|
作者
Xu, Beibei [1 ]
Luo, Zhipu [2 ]
Wilson, Andrew J. [3 ]
Chen, Ke [4 ]
Gao, Wenxiu [5 ]
Yuan, Guoliang [5 ]
Chopra, Harsh Deep [1 ]
Chen, Xing [6 ]
Willets, Katherine A. [3 ]
Dauter, Zbigniew [2 ]
Ren, Shenqiang [1 ]
机构
[1] Temple Univ, Dept Mech Engn, Temple Mat Inst, Philadelphia, PA 19122 USA
[2] Argonne Natl Lab, Synchrotron Radiat Res Sect, Macromol Crystallog Lab, Natl Canc Inst, 9700 S Cass Ave, Argonne, IL 60439 USA
[3] Temple Univ, Dept Chem, Philadelphia, PA 19122 USA
[4] Temple Univ, Dept Phys, Temple Mat Inst, Philadelphia, PA 19122 USA
[5] Nanjing Univ Sci Technol, Sch Mat Sci & Engn, Nanjing 210094, Jiangsu, Peoples R China
[6] Argonne Natl Lab, Div Energy Syst, 9700 S Cass Ave, Argonne, IL 60439 USA
基金
美国国家科学基金会;
关键词
ELECTRON-TRANSFER; TRANSFER COMPLEX; TRANSFER SALT; TTF-TCNQ; MULTIFERROICITY; FERROELECTRICITY; CONDUCTIVITY; METAL;
D O I
10.1002/adma.201600383
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Centimeter-sized segregated stacking TTF-C-60 single crystals are crystallized by a mass-transport approach combined with solvent-vapor evaporation for the first time. The intermolecular charge-transfer interaction in the long-range ordered superstructure enables the crystals to demonstrate external stimuli-controlled multifunctionalities and angle/electrical-potential-dependent luminescence.
引用
收藏
页码:5322 / +
页数:9
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