Multifunctional Charge-Transfer Single Crystals through Supramolecular Assembly

被引：27

作者：

Xu, Beibei ^{[1
]}

Luo, Zhipu ^{[2
]}

Wilson, Andrew J. ^{[3
]}

Chen, Ke ^{[4
]}

Gao, Wenxiu ^{[5
]}

Yuan, Guoliang ^{[5
]}

Chopra, Harsh Deep ^{[1
]}

Chen, Xing ^{[6
]}

Willets, Katherine A. ^{[3
]}

Dauter, Zbigniew ^{[2
]}

Ren, Shenqiang ^{[1
]}

机构：

[1] Temple Univ, Dept Mech Engn, Temple Mat Inst, Philadelphia, PA 19122 USA

[2] Argonne Natl Lab, Synchrotron Radiat Res Sect, Macromol Crystallog Lab, Natl Canc Inst, 9700 S Cass Ave, Argonne, IL 60439 USA

[3] Temple Univ, Dept Chem, Philadelphia, PA 19122 USA

[4] Temple Univ, Dept Phys, Temple Mat Inst, Philadelphia, PA 19122 USA

[5] Nanjing Univ Sci Technol, Sch Mat Sci & Engn, Nanjing 210094, Jiangsu, Peoples R China

[6] Argonne Natl Lab, Div Energy Syst, 9700 S Cass Ave, Argonne, IL 60439 USA

来源：

ADVANCED MATERIALS | 2016年 / 28卷 / 26期

基金：

美国国家科学基金会;

关键词：

ELECTRON-TRANSFER; TRANSFER COMPLEX; TRANSFER SALT; TTF-TCNQ; MULTIFERROICITY; FERROELECTRICITY; CONDUCTIVITY; METAL;

D O I：

10.1002/adma.201600383

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Centimeter-sized segregated stacking TTF-C-60 single crystals are crystallized by a mass-transport approach combined with solvent-vapor evaporation for the first time. The intermolecular charge-transfer interaction in the long-range ordered superstructure enables the crystals to demonstrate external stimuli-controlled multifunctionalities and angle/electrical-potential-dependent luminescence.

引用

页码：5322 / +

页数：9

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