The c-axis resistivity for two HOPG-based, first stage CuAl2Cl8 and second stage CuCl2-graphite intercalation compounds as a function of both pressure and temperature

被引:2
作者
Andersson, OE [1 ]
Sundqvist, B [1 ]
Polo, V [1 ]
Vangelisti, R [1 ]
Mareche, JF [1 ]
McRae, E [1 ]
机构
[1] UNIV NANCY 1,LAB CHIM SOLIDE MINERAL,CNRS,URA 158,F-54506 VANDOEUVRE NANCY,FRANCE
关键词
inorganic compounds; high pressure; electrical conductivity;
D O I
10.1016/0022-3697(95)00338-X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper we present data for the c-axis resistivity of first stage CuAl2Cl8 GIC and second stage CuCl2 GIC as functions of pressure, p, (0.0 < p < 1.5 GPa) and of temperature, T, (4 < T < 300 K). We show evidence of a possible new high-pressure phase above 1.0 GPa for the CuAl2Cl8 GIC and we show that the CuCl2 GIC is very stable at all pressures and temperature investigated. We make a comparison with previous results on SbCl5 GICs and other chloride intercalation compounds and with theories treating the temperature and pressure coefficients of transport parameters in layered solids.
引用
收藏
页码:719 / 723
页数:5
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