Water soluble new bimetallic catalyst [CuZn(bz)3(bpy)2]PF6 in hydrogen peroxide mediated oxidation of alcohols to aldehydes/ketones and C-N functional groups

被引：8

作者：

Syiemlieh, Ibanphylla ^{[1
]}

Asthana, Mrityunjaya ^{[2
,4
]}

Asthana, Sharad K. ^{[3
,5
]}

Kurbah, Sunshine D. ^{[1
]}

Koch, Angira ^{[1
]}

Lal, Ram A. ^{[1
]}

机构：

[1] North Eastern Hill Univ, Ctr Adv Study, Dept Chem, Shillong 793022, Meghalaya, India

[2] Indian Inst Technol, Dept Chem, Gauhati, Assam, India

[3] Banaras Hindu Univ, Dept Chem, Varanasi 221005, Uttar Pradesh, India

[4] TCG Life Sci Private Ltd, Kolkata 700091, India

[5] Babasaheb Bheemrao Ambedkar Univ, Dept Humaanities & Sci, Lucknow, Uttar Pradesh, India

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2018年 / 878卷

关键词：

Heterobimetallic Cu-Zn; Alcohols; Aldehydes; Ketones; Oxime; EPR; TRANSITION-METAL-FREE; CHEMOSELECTIVE AEROBIC OXIDATION; HIGHLY EFFICIENT OXIDATION; LIQUID-PHASE OXIDATION; ONE-POT CONVERSION; SELECTIVE OXIDATION; GALACTOSE-OXIDASE; MOLECULAR-OXYGEN; SECONDARY ALCOHOLS; ORGANIC FRAMEWORKS;

D O I：

10.1016/j.jorganchem.2018.10.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new heterobimetallic [CuZn(bz)(3)(bpy)(2)]PF6 has been synthesized from commercially available starting materials. Its structure has been established by molar conductance, magnetic moment, IR, electronic, ESR and X-ray crystallography. Its catalysis has been established in hydrogen peroxide mediated oxidation of alcohols to aldehydes and ketones and direct formation of oximes. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：48 / 59

页数：12

共 138 条

[1] Aerobic Copper-Catalyzed Organic Reactions [J].