CN-carbazole modified diphenylsilane-type high triplet energy hosts for blue phosphorescent organic light-emitting diodes

被引:5
作者
Yun, Ju Hui [1 ]
Han, Si Hyun [1 ]
Lee, Jun Yeob [1 ]
机构
[1] Sungkyunkwan Univ, Sch Chem Engn, 2066 Seobu Ro, Suwon 440746, Gyeonggi Do, South Korea
基金
新加坡国家研究基金会;
关键词
Host; Blue device; Phosphorescent device; Organic light-emitting diodes; Efficiency; EXTERNAL QUANTUM EFFICIENCY; LOW-DRIVING-VOLTAGE; ELECTROPHOSPHORESCENT DEVICES; ROLL-OFF; 30-PERCENT; DERIVATIVES; DOPANT; OLEDS;
D O I
10.1016/j.orgel.2018.08.028
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Diphenylsilane-derived high triplet energy host materials were developed by coupling diphenylsilane with CN-modified carbazoles. Two host materials with two CN-modified carbazoles or one CN-modified carbazole were synthesized, and their photophysical and device behavior were investigated. The host materials delivered a high triplet energy over 3.00 eV, a high glass transition temperature over 130 degrees C, ambipolar charge transport, and high external quantum efficiency over 20% as hosts of deep blue-emitting Ir emitters.
引用
收藏
页码:342 / 350
页数:9
相关论文
共 30 条
  • [11] Engineering the Substitution Position of Diphenylphosphine Oxide at Carbazole for Thermal Stability and High External Quantum Efficiency Above 30% in Blue Phosphorescent Organic Light-Emitting Diodes
    Kim, Mounggon
    Lee, Jun Yeob
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (26) : 4164 - 4169
  • [12] Deep blue phosphorescent organic light-emitting diodes using a Si based wide bandgap host and an Ir dopant with electron withdrawing substituents
    Kim, Sung Hyun
    Jang, Jyongsik
    Lee, Seok Jong
    Lee, Jun Yeob
    [J]. THIN SOLID FILMS, 2008, 517 (02) : 722 - 726
  • [13] Efficient blue phosphorescent organic light emitting diodes with host engineering
    Kim, Young Jae
    Son, Young Hoon
    Kim, Shin Hye
    Lee, Jung Min
    Lampande, Raju
    Noh, Chang Ho
    Kim, Sung Han
    Kwon, Jang Hyuk
    [J]. CURRENT APPLIED PHYSICS, 2015, 15 (01) : 42 - 47
  • [14] High Quantum Efficiency in Solution and Vacuum Processed Blue Phosphorescent Organic Light Emitting Diodes Using a Novel Benzofuropyridine-Based Bipolar Host Material
    Lee, Chil Won
    Lee, Jun Yeob
    [J]. ADVANCED MATERIALS, 2013, 25 (04) : 596 - 600
  • [15] An Exciplex Forming Host for Highly Effi cient Blue Organic Light Emitting Diodes with Low Driving Voltage
    Lee, Jeong-Hwan
    Cheng, Shuo-Hsien
    Yoo, Seung-Jun
    Shin, Hyun
    Chang, Jung-Hung
    Wu, Chih-I
    Wong, Ken-Tsung
    Kim, Jang-Joo
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (03) : 361 - 366
  • [16] Novel Ambipolar Orthogonal Donor-Acceptor Host for Blue Organic Light Emitting Diodes
    Leung, Man-kit
    Hsieh, Yu-Hsuan
    Kuo, Ting-Yi
    Chou, Pi-Tai
    Lee, Jiun-Haw
    Chiu, Tien-Lung
    Chen, Hsin-Jen
    [J]. ORGANIC LETTERS, 2013, 15 (18) : 4694 - 4697
  • [17] Incorporation of a CN group into mCP: a new bipolar host material for highly efficient blue and white electrophosphorescent devices
    Lin, Ming-Shiang
    Yang, Shang-Jung
    Chang, Hong-Wei
    Huang, Yi-Hsiang
    Tsai, Yu-Tang
    Wu, Chung-Chih
    Chou, Shu-Hua
    Mondal, Ejabul
    Wong, Ken-Tsung
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (31) : 16114 - 16120
  • [18] Deep-blue phosphorescent iridium complexes with picolinic acid N-oxide as the ancillary ligand for high efficiency organic light-emitting diodes
    Seo, Hoe-Joo
    Yoo, Kyung-Mo
    Song, Myungkwan
    Park, Jin Su
    Jin, Sung-Ho
    Kim, Young Inn
    Kim, Jang-Joo
    [J]. ORGANIC ELECTRONICS, 2010, 11 (04) : 564 - 572
  • [19] Highly efficient long-life blue fluorescent organic light-emitting diode exhibiting triplet-triplet annihilation effects enhanced by a novel hole-transporting material
    Suzuki, Tsunenori
    Nonaka, Yusuke
    Watabe, Takeyoshi
    Nakashima, Harue
    Seo, Satoshi
    Shitagaki, Satoko
    Yamazaki, Shunpei
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS, 2014, 53 (05)
  • [20] 4-Pyridyl-9,9′-spirobifluorenes as Host Materials for Green and Sky-Blue Phosphorescent OLEDs
    Thiery, Sebastien
    Tondelier, Denis
    Dedairieux, Celine
    Geffroy, Bernard
    Jeannin, Olivier
    Metivier, Remi
    Rault-Berthelot, Joelle
    Poriel, Cyril
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (11) : 5790 - 5805