A vibrational spectroscopic study of tengerite-(Y) Y2(CO3)3 2-3H2O

被引：2

作者：

Frost, Ray L. ^{[1
]}

Lopez, Andres ^{[1
]}

Wang, Lina ^{[1
,2
]}

Scholz, Ricardo ^{[3
]}

Sampaio, Ney Pinheiro ^{[4
]}

de Oliveira, Fernando A. N. ^{[5
]}

机构：

[1] Queensland Univ Technol, Fac Sci & Engn, Sch Chem Phys & Mech Engn, Brisbane, Qld 4001, Australia

[2] Tianjin Univ Technol, Sch Chem & Chem Engn, Tianjin, Peoples R China

[3] Univ Fed Ouro Preto, Sch Mines, Dept Geol, BR-3540000 Ouro Preto, MG, Brazil

[4] Univ Fed Ouro Preto, Sch Mines, NanoLab REDEMAT, BR-3540000 Ouro Preto, MG, Brazil

[5] Fed Inst Minas Gerais, BR-3540000 Ouro Preto, MG, Brazil

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2015年 / 137卷

基金：

澳大利亚研究理事会;

关键词：

Tengerite-(Y); Carbonate; Hydroxyl; Infrared and Raman spectroscopy; RARE-EARTH CARBONATES; SINGLE-CRYSTALS;

D O I：

10.1016/j.saa.2014.08.107

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The mineral tengerite-(Y) has been studied by vibrational spectroscopy. Multiple carbonate stretching modes are observed and support the concept of non-equivalent carbonate units in the tengerite-(Y) structure. Intense sharp bands at 464, 479 and 508 cm(-1) are assigned to YO stretching modes. Raman bands at 765 and 775 cm(-1) are assigned to the CO32- v(4) bending modes and Raman bands at 589, 611, 674 and 689 cm(-1) are assigned to the CO32- v(2) bending modes. Multiple Raman and infrared bands in the OH stretching region are observed, proving the existence of water in different molecular environments in the structure of tengerite-(Y). (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：612 / 616

页数：5

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