Synthesis, characterization, and catalytic applications of Ru(III) complexes containing N-[di(alkyl/aryl)carbamothioyl]benzamide derivatives and triphenylphosphine/triphenylarsine

被引：42

作者：

Gunasekaran, N. ^{[1
]}

Karvembu, R. ^{[1
]}

机构：

[1] Natl Inst Technol, Dept Chem, Tiruchirappalli 620015, Tamil Nadu, India

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 08期

关键词：

Ruthenium(III); Triphenylphosphine; OS donor ligand; Catalytic oxidation; NMO; RUTHENIUM(III) COMPLEXES; OXIDATION; ALCOHOLS;

D O I：

10.1016/j.inoche.2010.05.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Six coordinated ruthenium(III) complexes of the type [RuX2(L)(PPh3)(2)] or [RuX2(L)(AsPh3)(2)] {where L = N-[di(alkyl/aryl)carbamothioyl]benzamide derivatives, X = Cl or Br) have been prepared by the reaction between [RuX3(PPh3)(3)] or [RuX3(AsPh3)(3)] (where X = Cl or Br) and N-[di(alkyl/aryl)carbamothioyl] benzamide derivatives in toluene and characterized by elemental analysis, spectral data (electronic, IR and EPR) and magnetic moment studies. The complexes act as efficient catalysts for the oxidation of alcohols in presence of N-methylmorpholine-N-oxide as oxidant at room temperature. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：952 / 955

页数：4

共 20 条

[1] Ruthenium(II/III) bipyridine complexes incorporating thiol-based imine functions - Synthesis, spectroscopic and redox properties
Bhattacharyya, D
Chakraborty, S
Munshi, P
Lahiri, GK
[J]. POLYHEDRON, 1999, 18 (23) : 2951 - 2959
[2] Synthesis and characterization of Cu(II) and Ni(II) complexes of some 4-bromo- N -(di(alkyl/aryl)carbamothioyl) benzamide derivatives
Binzet, Gun
Kulcu, Nevzat
Floerke, Ulrich
Arslan, Hakan
[J]. JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (21) : 3454 - 3462
[3] COMPLEXES OF OSMIUM RUTHENIUM RHENIUM AND IRIDIUM HALIDES WITH SOME TERTIARY MONOPHOSPHINES AND MONOARSINES
CHATT, J
LEIGH, GJ
MINGOS, DMP
PASKE, RJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (11): : 2636 - &
[4] Oxidation of benzene with tert-butylhydroperoxide catalyzed by a novel [RuIII(amp)(bipy)(H2O)]+ complex:: first report of homogeneously catalyzed oxo-transfer reaction in benzene oxidation
Chatterjee, D
Mitra, A
Mukherjee, S
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 165 (1-2) : 295 - 298
[5] Mild oxidation of alcohols with periodic acid catalyzed by [Ru(acac)2(CH3CN)2]PF6 in water
Ganesamoorthy, S.
Shanmugasundaram, K.
Karvembu, R.
[J]. CATALYSIS COMMUNICATIONS, 2009, 10 (14) : 1835 - 1838
[6] Acetato and acetylacetonato ruthenium(II) complexes containing SbPri,3, PPri,3 and PCy3 as ligands
Grunwald, C
Laubender, M
Wolf, J
Werner, H
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (05): : 833 - 839
[7] LOW SPIN FERRIC HEMOGLOBIN COMPLEXES
HARRIS, G
[J]. THEORETICA CHIMICA ACTA, 1966, 5 (05): : 379 - &
[8] Synthesis, characterization and catalytic activities of ruthenium complexes containing triphenylphosphine/triphenylarsine and tetradentate Schiff bases
Karvembu, R
Hemalatha, S
Prabhakaran, R
Natarajan, K
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (05) : 486 - 490
[9] Oxidation of alcohols with nitroxyl radical under polymer-supported two-phase conditions
Kashiwagi, Y
Chiba, S
Anzai, J
[J]. NEW JOURNAL OF CHEMISTRY, 2003, 27 (11) : 1545 - 1549
[10] LEVER ABP, 1984, ELECT SPECTRA DN ION, P376

← 1 2 →