Direct synthesis of non-breathing MIL-53(Al)(ht) from a terephthalate-based ionic liquid as linker precursor

被引：19

作者：

Fischer, Marcus ^{[1
]}

Schwegler, Johannes ^{[2
]}

Paula, Carolin ^{[1
]}

Schulz, Peter S. ^{[2
]}

Hartmann, Martin ^{[1
]}

机构：

[1] Friedrich Alexander Univ Erlangen Nurnberg, Erlangen Catalysis Resource Ctr, Egerlandstr 3, D-91058 Erlangen, Germany

[2] Friedrich Alexander Univ Erlangen Nurnberg, Inst Chem React Engn, Egerlandstr 3, D-91058 Erlangen, Germany

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 46期

关键词：

METAL-ORGANIC FRAMEWORKS; MIL-53; SEPARATION;

D O I：

10.1039/c6dt03930h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An organic imidazolium salt of terephthalic acid has been utilized as a linker precursor for the synthesis of an aluminum-based metal organic framework (MOF) with MIL-53(ht) structure. This material shows the predicted porosity in terms of nitrogen and hydrogen sorption without exhibiting the breathing effect typical for MIL-53 (Al) materials.

引用

页码：18443 / 18446

页数：4

共 12 条

[1] MIL-53(Al) under reflux in water: Formation of γ-AlO(OH) shell and H2BDC molecules intercalated into the pores [J].

Bezverkhyy, Igor ;

Ortiz, Guillaume ;

Chaplais, Gerald ;

Marichal, Claire ;

Weber, Guy ;

Bellat, Jean-Pierre .

MICROPOROUS AND MESOPOROUS MATERIALS, 2014, 183 :156-161

[2] Adsorptive separation of isobutene and isobutane on Cu3(BTC)2 [J].

Hartmann, Martin ;

Kunz, Sebastian ;

Himsl, Dieter ;

Tangermann, Oliver ;

Ernst, Stefan ;

Wagener, Alex .

LANGMUIR, 2008, 24 (16) :8634-8642

[3] Solid-state 1H and 27Al NMR studies of amorphous aluminum hydroxides [J].

Isobe, T ;

Watanabe, T ;

de la Caillerie, JBD ;

Legrand, AP ;

Massiot, D .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2003, 261 (02) :320-324

[4] Environmentally friendly synthesis of highly hydrophobic and stable MIL-53 MOF nanomaterials [J].

Liu, Jia ;

Zhang, Feng ;

Zou, Xiaoqin ;

Yu, Guangli ;

Zhao, Nian ;

Fan, Songjie ;

Zhu, Guangshan .

CHEMICAL COMMUNICATIONS, 2013, 49 (67) :7430-7432

[5] A rationale for the large breathing of the porous aluminum terephthalate (MIL-53) upon hydration [J].

Loiseau, T ;

Serre, C ;

Huguenard, C ;

Fink, G ;

Taulelle, F ;

Henry, M ;

Bataille, T ;

Férey, G .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (06) :1373-1382

[6]

Massonne K. B., 2012, Eur. Pat. Appl, Patent No. [EP2532646A1, 2532646]

[7] Structural Phase Transitions and Thermal Hysteresis in the Metal-Organic Framework Compound MIL-53 As Studied by Electron Spin Resonance Spectroscopy [J].

Mendt, Matthias ;

Jee, Bettina ;

Stock, Norbert ;

Ahnfeldt, Tim ;

Hartmann, Martin ;

Himsl, Dieter ;

Poeppl, Andreas .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (45) :19443-19451

[8] High-Separation Performance of Chromatographic Capillaries Coated with MOF-5 by the Controlled SBU Approach [J].

Muench, Alexander S. ;

Seidel, Juergen ;

Obst, Anja ;

Weber, Edwin ;

Mertens, Florian O. R. L. .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (39) :10958-10964

[9] Ionothermal synthesis of zeolites, metal-organic frameworks, and inorganic-organic hybrids [J].

Parnham, Emily R. ;

Morris, Russell E. .

ACCOUNTS OF CHEMICAL RESEARCH, 2007, 40 (10) :1005-1013

[10] Modulated Synthesis of Zr-Based Metal-Organic Frameworks: From Nano to Single Crystals [J].

Schaate, Andreas ;

Roy, Pascal ;

Godt, Adelheid ;

Lippke, Jann ;

Waltz, Florian ;

Wiebcke, Michael ;

Behrens, Peter .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (24) :6643-6651

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