Synthesis and crystal structure of a heterobinuclear complex [(PhPPy2)2PdCuCl2]ClO4 (PhPPy2=bis(2-pyridyl)phenylphosphine)

被引：7

作者：

Zhang, TL ^{[1
]}

Qin, Y

Wu, DY

Wang, CG

Liu, CL

机构：

[1] Huazhong Univ Sci & Technol, Dept Chem, Wuhan 430074, Hubei, Peoples R China

[2] Huazhong Normal Univ, Dept Chem, Wuhan 430079, Hubei, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 58卷 / 16期

关键词：

palladium(II)-copper(I) complex; crystal structure; 2-pyridylphosphine ligand;

D O I：

10.1080/00958970500236621

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mononuclear palladium(II) complex trans-[PdCl2(PhPPy2)(2)] (1) reacts with [Cu(CH3CN)(4)]ClO4 to afford the heterobinuclear [(PhPPy2)(2)PdCuCl2]ClO(4)center dot 2CH(3)CN (2), bridged by two PhPPy2 ligands in a new mode. Complex 2 crystallizes in space group P2(1)/c with a = 12.947(1), b = 9.142(1), c = 33.454(2) angstrom, beta = 99.698(1)degrees. The copper(I) and palladium(II) ions in 2 adopt distorted tetrahedral and square-planar geometry, respectively. At room temperature, the complex is photoluminescent in solution.

引用

页码：1485 / 1491

页数：7

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