Revisiting Al-Ni-Zr bulk metallic glasses using the 'cluster-resonance' model

被引:21
作者
Li FengWei [1 ]
Qiang JianBing [1 ]
Wang YingMin [1 ]
Wang Qing [1 ]
Dong XingLong [1 ]
Dong Chuang [1 ]
机构
[1] Dalian Univ Technol, Minist Educ, Key Lab Mat Modificat, Dalian 116024, Peoples R China
来源
CHINESE SCIENCE BULLETIN | 2011年 / 56卷 / 36期
基金
中国国家自然科学基金;
关键词
bulk metallic glass; glass-forming ability; Al-Ni-Zr; cluster formula; MECHANICAL-PROPERTIES; SUPERCOOLED LIQUID; FORMING ABILITY; ALLOYS;
D O I
10.1007/s11434-011-4842-z
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Six series of alloys, namely, Ni3Zr6Al (x) , Ni3Zr7Al (x) , Ni4Zr9Al (x) , Ni3Zr8Al (x) , Ni3Zr9Al (x) and Ni3Zr10Al (x) (x=1, 1.5, 2, 3) were designed in this work and the bulk metallic glass (BMG) formation of these compositions was investigated by copper mold suction casting. A centimeter-scale BMG sample was obtained for the Ni4Zr9Al2 (Al13.3Ni26.7Zr60 in atomic percent) composition. The thermal glass parameters for this BMG were determined to be Delta T (x) = 68 K, T (rg) = 0.579, and gamma (m) = 0.689. Using the 'cluster-resonance' model for glass formation an optimal BMG composition was determined using the cluster formula [Ni3Zr9](Al2Ni1).
引用
收藏
页码:3902 / 3907
页数:6
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