The first metal complexes of 4,4′-biimidazole and 4,4′-biimidazolate with hydrogen-bonding networks on the Cu(II) complexes:: 1-D structures by N-H•••X•••H-N hydrogen-bonding

被引:20
|
作者
Morita, Y [1 ]
Murata, T
Fukui, K
Tadokoro, M
Sato, K
Shiomi, D
Takui, T
Nakasuji, K
机构
[1] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan
[2] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, Osaka 5588585, Japan
[3] Osaka City Univ, Grad Sch Sci, Dept Mat Sci, Sumiyoshi Ku, Osaka 5588585, Japan
关键词
D O I
10.1246/cl.2004.188
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Cu(II) complexes based on 4,4'-biimidazole and its deprotonated mono-anionic ligands were synthesized as the first metal complexes, which exhibit hydrogen-bonding networks. X-ray crystal structure analyses reveal the pi-stacking structure of each complex and N-H...X or N...H-X type hydrogen-bondings.
引用
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页码:188 / 189
页数:2
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