Two new mononuclear Ni(II) complexes with reduced ONNO type Schiff base

被引：4

作者：

Durmus, S

Tatar, L

Arici, C ^{[1
]}

Dinçer, N

Atakol, O

Svoboda, I

Fuess, H

机构：

[1] Hacettepe Univ, Dept Engn Phys, TR-06800 Ankara, Turkey

[2] Abant Izzet Baysal Univ, Fac Educ, Dept Chem, Golkoy, Bolu, Turkey

[3] Mersin Univ, Fac Pharm, Mersin, Turkey

[4] Ankara Univ, Dept Chem, Fac Sci, Ankara, Turkey

[5] Tech Univ Darmstadt, D-64287 Darmstadt, Germany

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 2005年 / 220卷 / 11期

关键词：

mononuclear Ni complexes; cyclic voltammetry; single crystal structure analysis; X-ray diffraction;

D O I：

10.1524/zkri.2005.220.11_2005.977

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

N,N'-bis(salicylidene)-1,3-propanediamine (LH2) and N,N'-bis(salicylidene)-2,2'-dimethyl-1,3-propanediamine (DMLH2) were reduced to phenolic amines by using NaBH4. Mononuclear complexes were obtained with Ni (II) in a N3O6 coordination sphere with these amines and N3- ions, in DMF media. It was established with the XRD studies that the coordination spheres were distorted octahedral and the complex obtained with LH2 formed dimeric structures via phenolic OH bonds. The other complex was seen to have monomeric structure. The complexes were characterized by X-ray diffraction, elemental analysis, termogravimetry, IR spectroscopy and simple magnetic susceptibility (Gouy method). In addition, cyclic voltammetric studies have been performed.

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页码：977 / 982

页数：6

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