Conducting radical salts of the new electron donor bis(1.3-cyclobutylenedithio)tetrathiafulvalene

被引：0

作者：

Klausa, T

Heinen, I

Hübler, M

Keller, HJ

Kircher, P

Löb, I

Milbredt, C

Pritzkow, H

Schiller, M

Schmidt, W

Schweitzer, D

Strunz, W

机构：

[1] Univ Stuttgart, Inst Phys 3, D-70550 Stuttgart, Germany

[2] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

SYNTHETIC METALS | 2001年 / 122卷 / 02期

关键词：

BEDT-TTF; electrocrystallization methods; bis(1.3-cylobutylenedithio)tetrathiafulvalene;

D O I：

10.1016/S0379-6779(00)00303-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The new pi -electron donor bis(1.3-cylobutylenedithio)tetrathiafulvalene (1.3-CBDT-TTF), which is only slightly different in the periphery of the molecule with respect to the well-known donor BEDT-TTF was synthesized. The molecular structure has been characterized and the electrochemical behavior of this new donor was investigated. New cation radical salts were prepared by electrocrystallization methods. The structures of (1.3-CBDT-TTF)I-2, (1.3-CBDT-TtF)(2)[AuI2], (1.3-CBDT-TTF)(x)(ReO4)(y) and (1.3-CBDT-TTF)(2)PF6.THF were characterized by X-ray analyses. The room temperature electrical resistivities of the radical salts are low and range between 0.5 and 5 Omega cm. (C) 2001 Elsevier Science B.V, All rights reserved.

引用

页码：279 / 286

页数：8

共 16 条

[1] SYNTHESIS AND STRUCTURE OF ZETA-(BEDT-TTF)2(I3)(I5) AND (BEDT-TTF)2(I3)(TIL4) - COMPARISON OF THE ELECTRICAL-PROPERTIES OF ORGANIC CONDUCTORS DERIVED FROM CHEMICAL OXIDATION VS ELECTROCRYSTALLIZATION [J].