Electron paramagnetic resonance investigation of phosphorus and nitrogen in [60]fullerene

被引：0

作者：

Knapp, C ^{[1
]}

Adla, A ^{[1
]}

Weiden, N ^{[1
]}

Kaas, H ^{[1
]}

Dinse, KP ^{[1
]}

Pietzak, B ^{[1
]}

Waiblinger, M ^{[1
]}

Weidinger, A ^{[1
]}

机构：

[1] Tech Univ Darmstadt, D-64287 Darmstadt, Germany

来源：

ELECTRONIC PROPERTIES OF NOVEL MATERIALS - PROGRESS IN MOLECULAR NANOSTRUCTURES: XII INTERNATIONAL WINTERSCHOOL | 1998年 / 442卷

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Atomic Nitrogen and Phosphorus can be encapsulated in fullerenes acting as highly stable chemical traps. In solution, the neutral atoms in their quartet spin ground state are weakly coupled to the surrounding by zero-field-splitting interaction, resulting either from collision-induced deformations of the fullerene cage or by intrinsic deviations from spherical symmetry. From an analysis of the spin relaxation times, values for the correlation time and the mean square value of the interaction can be deduced.

引用

页码：383 / 387

页数：5