Palladium-Catalyzed Cross-Coupling of H-Phosphinate Esters with Chloroarenes

被引：118

作者：

Deal, Eric L. ^{[1
]}

Petit, Christelle ^{[1
]}

Montchamp, Jean-Luc ^{[1
]}

机构：

[1] Texas Christian Univ, Dept Chem, Ft Worth, TX 76129 USA

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 12期

基金：

美国国家科学基金会;

关键词：

PHOSPHORUS-CARBON BOND; ELEMENTAL PHOSPHORUS; RECEPTOR ANTAGONISTS; WHITE PHOSPHORUS; P-4; ACTIVATION; P-ARYLATION; ACIDS; ARYL; DERIVATIVES; HYDROPHOSPHINYLATION;

D O I：

10.1021/ol201222n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The palladium-catalyzed cross-coupling reaction between H-phosphinate esters and chloroarenes or chloroheteroarenes Is described. This reaction is the first general metal-catalyzed phosphorus carbon bond-forming reaction between a phosphorus nucleophile and chloroarenes.

引用

页码：3270 / 3273

页数：4

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