Compatibility and viscosity of polycarbonate-poly(methyl methacrylate) blend

被引:0
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作者
Avdeev, NN
Makarova, VV
Kotomin, SV
Kulichikhin, VG
Kuleznev, VN
机构
[1] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 117912, Russia
[2] Lomonosov Moscow State Acad Fine Chem Technol, Moscow 117571, Russia
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中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The compatibility of components in the PC (M-w = 2.5 x 10(4))-PMMA (M-w = 1.5 x 10(4), 7.4 x 10(4), 30 x 10(4)) blend at a temperature above the T-g of PC was studied by the microinterference method. The constructed phase diagrams are shown to contain an UCST. For the PC-PMMA system (M-w = 1.5 x 10(4)), the kinetics of diffusion mixing and viscosity properties (at T = 240 degreesC) were characterized at different points of the phase diagram. The corresponding dependence of viscosity on composition shows a local minimum near a binodal at a higher content of PC.
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页码:112 / 117
页数:6
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