Photo-oxidation of thioacetamide by uranyl ions

被引:0
|
作者
Vaidya, VK [1 ]
Kabra, BV [1 ]
Sharma, RP [1 ]
Choudhry, P [1 ]
机构
[1] MLV GOVT AUTONOMOUS COLL,DEPT CHEM,BHILWARA 311001,INDIA
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Photo-oxidation of thioacetamide by uranyl ions in presence of perchloric acid has been studied, at pH 2.0. Acetamide. sulphur and sulphur dioxide have been characterized as the products. The intermediacy of uranium(V) has been proved spectrophotometrically. A mechanism has been proposed involving excited state charge transfer complex (exciplex) formation.
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页码:513 / 516
页数:4
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