Synthesis and binding property of a novel tripodal hexadentate ligand having catechol moieties

被引：12

作者：

Hayashi, M ^{[1
]}

Hiratani, K ^{[1
]}

Kina, SI ^{[1
]}

Ishii, M ^{[1
]}

Saigo, K ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Bunkyo Ku, Tokyo 1138656, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 34期

关键词：

host compound; ionophore; rearrangement; iron and compounds;

D O I：

10.1016/S0040-4039(98)01278-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel tripodal hexadentate ligand, consisting of three catechol units, three isobutenyl ether arms, and one aromatic core, was synthesized through four steps, in which the Claisen rearrangement was included as the key step. The hexadentate ligand formed a 1:1 complex with iron(III) trichloride hexahydrate with an equilibrium constant (conditional) of 6.3 x 10(4) M-1 in acetonitrile in the presence of 2,4,6-trimethylpyridine. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：6211 / 6214

页数：4

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