Rhodium-catalyzed [5+2] cycloaddition reactions in water

被引：44

作者：

Wender, PA ^{[1
]}

Love, JA ^{[1
]}

Williams, TJ ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

SYNLETT | 2003年 / 09期

关键词：

water-soluble catalyst; biphasic reactions; cycloaddition; medium-sized rings; rhodium;

D O I：

10.1055/s-2003-40357

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new water-soluble rhodium catalyst is reported along with its ability to effect [5+2] cycloaddition reactions in water. This water-soluble catalyst is recyclable, is readily separated from the organic product, and allows one to avoid or minimize the use of organic solvents, the major waste stream of most organic reactions.

引用

收藏

页码：1295 / 1298

页数：4

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