Direct ion exchange of Tris(2,2′-bipyridine)ruthenium(II) into an α-zirconium phosphate framework

被引：97

作者：

Marti, AA ^{[1
]}

Colón, JL ^{[1
]}

机构：

[1] Univ Puerto Rico, Dept Chem, Rio Piedras, PR 00931 USA

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 09期

关键词：

D O I：

10.1021/ic025548g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first direct ion exchange of a luminescent metal complex into an alpha-zirconium phosphate framework has been accomplished. A hydrated form of alpha-ZrP, with an expanded 10.3 Angstrom interlayer distance, has been used for the intercalation of Ru(bpy)(3)(2+), resulting in further expansion to 15.2 Angstrom. The Ru(bpy)(3)(2+) luminescence band is slightly blue-shifted. High Ru(bpy)(3)(2+) loadings lead to luminescence self-quenching.

引用

页码：2830 / 2832

页数：3

共 14 条

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