Direct ion exchange of Tris(2,2′-bipyridine)ruthenium(II) into an α-zirconium phosphate framework

被引:97
作者
Marti, AA [1 ]
Colón, JL [1 ]
机构
[1] Univ Puerto Rico, Dept Chem, Rio Piedras, PR 00931 USA
关键词
D O I
10.1021/ic025548g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The first direct ion exchange of a luminescent metal complex into an alpha-zirconium phosphate framework has been accomplished. A hydrated form of alpha-ZrP, with an expanded 10.3 Angstrom interlayer distance, has been used for the intercalation of Ru(bpy)(3)(2+), resulting in further expansion to 15.2 Angstrom. The Ru(bpy)(3)(2+) luminescence band is slightly blue-shifted. High Ru(bpy)(3)(2+) loadings lead to luminescence self-quenching.
引用
收藏
页码:2830 / 2832
页数:3
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