Advances in zeolite-supported metal catalysts for propane dehydrogenation

被引：51

作者：

Qu, Ziqiang ^{[1
]}

Sun, Qiming ^{[1
]}

机构：

[1] Soochow Univ, Innovat Ctr Chem Sci, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

来源：

INORGANIC CHEMISTRY FRONTIERS | 2022年 / 9卷 / 13期

基金：

中国国家自然科学基金;

关键词：

LIGHT ALKANE DEHYDROGENATION; OXIDATIVE DEHYDROGENATION; SILICALITE-1; ZEOLITE; ALLOY NANOPARTICLES; SUBNANOMETRIC CLUSTERS; REACTION PERFORMANCE; MESOPOROUS ZEOLITE; PROPYLENE; PLATINUM; ZSM-5;

D O I：

10.1039/d2qi00653g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Propylene is one of the building blocks in modern industry and the feedstock for polypropylene, acrylonitrile, and other important chemicals. Propane dehydrogenation (PDH) is one of the most promising on-purpose technologies to produce propylene, and thus has attracted widespread attention from both the academic and industrial communities. In recent years, zeolite-supported metal catalysts have exhibited excellent activity and superhigh stability in PDH reactions, which even exceed that of industrial catalysts, suggesting their great application prospects. In this review, we present a comprehensive summary of the latest research progress in the synthesis of state-of-the-art zeolite-supported metal catalysts, including monometal catalysts, bimetal catalysts, and single-site catalysts, and their outstanding catalytic activity in PDH reactions. Also, their advanced characterization techniques, catalytic mechanisms, and structure-function relationships are introduced simultaneously. Finally, some current limitations and future perspectives in the field of zeolite-supported metal catalysts for PDH processes are proposed. It is expected that this review will provide references and give insights into the future design of highly efficient zeolite-supported metal catalysts for PDH applications.

引用

页码：3095 / 3115

页数：21

共 134 条

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