Urea derivatives enhance the photocatalytic activity of dye-modified titanium dioxide

被引:32
作者
Fueldner, Stefan [1 ]
Mitkina, Tatiana [1 ]
Trottmann, Tobias [1 ]
Frimberger, Alexandra [1 ]
Gruber, Michael [2 ]
Koenig, Burkhard [1 ]
机构
[1] Univ Regensburg, Inst Organ Chem, D-93040 Regensburg, Germany
[2] Univ Hosp Regensburg, Dept Anaesthesia, D-93051 Regensburg, Germany
关键词
PHOTOINDUCED REDUCTION; PROTON-TRANSFER; VISIBLE-LIGHT; CO2; REDUCTION; WATER; TIO2; MECHANISM; PLATINUM; HYDROGEN; NANOPARTICLES;
D O I
10.1039/c0pp00374c
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Trace amounts of urea derivatives enhance the rate of nitrobenzene N3-sensitized TiO2 photoreduction by catalyzing the proton transfer. The usually required addition of transition metal co-catalysts becomes dispensable for this visible light photocatalysis, facilitating its application in organic synthesis.
引用
收藏
页码:623 / 625
页数:3
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