Kinetics and mechanism of electron transfer reactions: Oxidation of hypophosphorus acid by peroxodisulphate induced by irradiation with visible light in an aqueous solution containing tris(2,2'-bipyridine) ruthenium(II) ion

被引：0

作者：

Bansal, S. ^{[1
]}

Soni, N. K. ^{[1
]}

Khandelwal, C. L. ^{[1
]}

Sharma, P. D. ^{[1
]}

机构：

[1] Univ Rajasthan, Dept Chem, Jaipur 302004, Rajasthan, India

来源：

OXIDATION COMMUNICATIONS | 2007年 / 30卷 / 04期

关键词：

electron transfer reaction; oxidation; hypophosphorus acid; irradiation; peroxodisulphate;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of oxidation of hypophosphorous acid by peroxodisulphate in the presence of photocatalyst [Ru(bipy)(3)(2+)] induced by irradiation with visible light indicates the following rate law: [GRAPHICS] where k(q) and k(0) are the quenching and excitation rate constants, respectively.

引用

页码：772 / 777

页数：6

共 9 条

[1] Laser flash photolysis studies of tris(2,2′-bipyridine)nickel(II) ion in aqueous solution
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INORGANICA CHIMICA ACTA, 2011, 372 (01) : 429 - 435
[2] PHOTOINDUCED INTERMOLECULAR AND INTRAMOLECULAR ELECTRON-TRANSFER REACTIONS OF CARBOXYLATOPENTAAMMINECOBALT(III) AND EXCITED-STATE TRIS(2,2'-BIPYRIDINE) RUTHENIUM(II) COMPLEXES
RAMARAJ, R
THOMAS, CC
PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES, 1991, 103 (06): : 735 - 740
[3] KINETICS AND MECHANISM OF 1,10-PHENANTHROLINE AND 2,2′-BIPYRIDINE-CATALYSED OXIDATION OF TRIS(1,10-PHENANTHROLINE)-IRON(II) AND TRIS(2,2′-BIPYRIDINE)IRON(II) BY CHROMIUM(VI) IN SULPHURIC ACID MEDIUM
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[4] An Insight into the Kinetics and Mechanism of Oxidation of Tris(4,4'-dimethyl-2,2'-bipyridine)iron(II) by Bromate
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Shamim, Afshan
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RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2020, 94 (03) : 544 - 550
[5] An Insight into the Kinetics and Mechanism of Oxidation of Tris(4,4'-dimethyl-2,2'-bipyridine)iron(II) by Bromate
Afshan Shazia Summer
Rozina Shamim
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Russian Journal of Physical Chemistry A, 2020, 94 : 544 - 550
[6] Kinetics and mechanism of electron-transfer reactions: ruthenium(III) chloride catalyzed oxidation of aspartic acid by peroxomonosulfate ion in acidic medium
Sailani, Riya
Sharma, Mridula
Pareek, Deepmala
Khandelwal, C. L.
Sharma, P. D.
REACTION KINETICS MECHANISMS AND CATALYSIS, 2012, 105 (02) : 249 - 259
[7] Kinetics and mechanism of electron-transfer reactions: ruthenium(III) chloride catalyzed oxidation of aspartic acid by peroxomonosulfate ion in acidic medium
Riya Sailani
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Reaction Kinetics, Mechanisms and Catalysis, 2012, 105 : 249 - 259
[8] Kinetics and mechanism of electron transfer reactions in acid perchlorate medium. Hydrogen ion dependence on the rate of oxidation of formic acid by thallium perchlorate catalyzed by ruthenium (III) chloride in acid aqueous medium
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Dubey, S
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OXIDATION COMMUNICATIONS, 2000, 23 (02): : 246 - 254
[9] Kinetics and mechanism of 2,2′-bipyridine and 1,10-phenanthroline catalysed oxidation of bis(2,2′,6′,2"-terpyridine)iron(II) by chromium(VI) in sulphuric acid medium
Reddy, K. P. P. R. Mohan
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Reddy, R. N.
OXIDATION COMMUNICATIONS, 2008, 31 (02): : 373 - 379

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