Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst

被引：105

作者：

Ribeiro, A. P. C. ^{[1
]}

Martins, L. M. D. R. S. ^{[1
,2
]}

Pombeiro, A. J. L. ^{[1
]}

机构：

[1] Univ Lisbon, Ctr Quim Estrut, Inst Super Tecn, Ave Rovisco Pais, P-1049001 Lisbon, Portugal

[2] Inst Politecn Lisboa, Chem Engn Dept, Inst Super Engn Lisboa, Rua Conselheiro Emidio Navarro, P-1959007 Lisbon, Portugal

来源：

GREEN CHEMISTRY | 2017年 / 19卷 / 20期

关键词：

RUTHENIUM PINCER COMPLEXES; COMPUTATIONAL DESIGN; CYCLOHEXANE OXIDATION; MECHANISTIC INSIGHTS; CO2; HYDROGENATION; METAL CATALYSTS; BICARBONATES; FORMAMIDES; REDUCTION; PEROXIDE;

D O I：

10.1039/c7gc01993a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The highly efficient eco-friendly synthesis of methanol (44% yield, TONs up to 2.3 x 10(3)) directly from carbon dioxide is achieved by using H-2 and the iron(II) scorpionate catalyst [FeCl2{kappa(3)- HC(pz)(3)}] (pz = pyrazol-1-yl) in a solvent- or amine-free mild new protocol.

引用

页码：4811 / 4815

页数：5

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