Synthesis and characterization of new titanium hexanuclear oxo carboxylato alkoxides.: Molecular structure of [Ti6(μ3-O)6-(μ-O2CC6H4OPh)6(OEt)6]

被引：55
|
作者：
Papiernik, R
Hubert-Pfalzgraf, LG
Vaissermann, J
Goncalves, MCHB
机构：
[1] URA CNRS, Lab Chim Mol, F-06108 Nice, France
[2] URA CNRS, Lab Chim Metaux Transit, F-75252 Paris, France
[3] Univ Tecn Lisboa, Dept Engn Mat, Inst Super Tecn, P-1096 Lisbon, Portugal
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 14期
关键词：
D O I：
10.1039/a803266a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction between Ti(OR)(4) (R = Et or Pr-i) and 2-phenoxybenzoic acid in refluxing toluene led to [Ti-6(mu(3)-O)(6)(mu-O2CC6H4OPh)(6)(OR)(6)]; its structure corresponds to an assembly of two staggered triangular units sharing six edges (actually the mu(3)-O ligands) and connected via the carboxylate ligands.
引用
收藏
页码：2285 / 2287
页数：3
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