Petrology and Raman spectroscopy of high pressure phases in the Gujba CB chondrite and the shock history of the CB parent body

High pressure phases majorite, possibly majorite-pyrope(ss), wadsleyite, and coesite are present in the matrix and in barred olivine fragments in the Gujba CB chondrite. Grossular-pyrope was also observed in some small inclusions. The CB chondrites are metal-rich meteorites with characteristics that sharply distinguish them from other chondrite groups. All of the CB chondrites contain impact melt regions interstitial to their chondrules, fragments and metal and a major impact event (or events), on the CB chondrite parent body is clearly a significant stage in its history. We studied three areas interstitial to chondrules and metal in the Gujba CBa chondrite. From Raman spectra, the barred olivine fragments and matrix in these regions have various combinations of olivine and low-Ca pyroxene, as well as majorite garnet (Mg4Si4O12), a phase that forms by high-pressure transformation of low-Ca pyroxene and wadsleyite, a high pressure product of olivine. Compositions of the majorite suggest both majorite and majorite-pyrope solid solution may be present. The mineral assemblage of majorite and wadsleyite suggest minimum shock pressures and temperatures of similar to 19 GPa and similar to 2000 degrees C, respectively. The occurrences of high pressure phases are variable from one area to another, on the scale of millimeters or less, suggesting heterogeneous distribution of shock and/or back transformation to low pressure polymorphs throughout the meteorite. The high pressure phases record a high temperature-pressure impact event that is superimposed onto, and thus postdates formation of, the chondrules and other components in the CB chondrites. The barred chondrules and metal in the CB chondrites are primary materials formed prior to the impact event either generated in an earlier planetesimal scale impact event or in the nebula.