Bidentated hydrogen bond from [O-H•••N-N•••H-O] to [O-•••+H-N-N-H+•••-O] structures in solids

被引：15

作者：

Akutagawa, T ^{[1
]}

Uchimaru, T

Sakai, K

Hasegawa, T

Nakamura, T

机构：

[1] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0600812, Japan

[2] JST, PRESTO, Kawaguchi 3320012, Japan

[3] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 2003年 / 107卷 / 26期

关键词：

D O I：

10.1021/jp027219f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Heteronuclear bidentated N-H-O hydrogen bonds in the (4,4'-bipyridine)(polynitrophenols)(2) system were revealed in terms of X-ray structural analyses, ab-initio calculations, and vibrational spectra. 4,4'-Bipyridine (AA) and polynitrophenols (D) acted as Bronsted base and acid in solids, respectively. The bidentated hydrogenbonding interaction in solids was modified between [D-...+H-AA-H+...-D] and [D-H(...)AA(...)H-D] through regulating Bronsted acid-base conditions.

引用

页码：6248 / 6251

页数：4

共 30 条

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Albert B., 1994, Molecular Biology of the Cell, V3

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