High-pressure behaviour of Cs2V3O8 fresnoite

被引:5
作者
Grzechnik, Andrzej [1 ]
Yeon, Jeongho [2 ]
Loye, Hans-Conrad Zur [2 ]
Friese, Karen [3 ]
机构
[1] Rhein Westfal TH Aachen, Inst Crystallog, D-52066 Aachen, Germany
[2] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
[3] Forschungszentrum Julich, Julich Ctr Neutron Sci, D-52425 Julich, Germany
关键词
Fresnoites; Mixed-valence vanadates; High pressure; Crystal structure; Phase transitions; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; VANADIUM-OXIDES; PHASE-TRANSITION; DIFFRACTION; ELECTRON; VANADATE; GROWTH;
D O I
10.1016/j.jssc.2016.03.041
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Crystal structure of Cs2V3O8 fresnoite (P4bm, Z=2) has been studied using single-crystal X-ray diffraction in a diamond anvil cell to 8.6 GPa at room temperature. Cs2V3O8 undergoes a reversible first-order phase transition at about 4 GPa associated with anomalies in the pressure dependencies of the lattice parameters and unit-cell volume but without any symmetry change. Both structures consist of layers of corner-sharing V-5+O-4 tetrahedra and V-4+O-5 tetragonal pyramids separated by the Cs+ cations located between the layers. At low pressures, the compression has little effect on the polarity of the structure. Above 4 GPa, the pseudosymmetry with respect to the corresponding centrosymmetric space group P4/mbm abruptly increases. The effects of external pressure and of the A(+) cation substitution in the vanadate fresnoites A(2)V(3)O(8) (A(+): K+, Rb+, NH4+, Cs+) are discussed. (C) 2016 Elsevier Inc. All rights reserved.
引用
收藏
页码:252 / 258
页数:7
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