Catalysts for methanol steam reforming-A review

被引：698

作者：

Sa, Sandra ^{[1
]}

Silva, Hugo ^{[1
]}

Brandao, Lucia ^{[1
]}

Sousa, Jose M. ^{[1
,2
]}

Mendes, Adelio ^{[1
]}

机构：

[1] Univ Porto, Fac Engn, LEPAE, Dept Engn Quim, P-4200465 Oporto, Portugal

[2] Univ Tras Os Montes & Alto Douro, Dept Quim, P-5001911 Vila Real Codex, Portugal

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2010年 / 99卷 / 1-2期

关键词：

Catalysts; Hydrogen; Methanol steam reforming; SUPPORTED PD CATALYSTS; COPPER-BASED CATALYSTS; CU-BASED CATALYSTS; HYDROGEN-PRODUCTION; FUEL-CELL; MEMBRANE REACTOR; CU/ZNO/AL2O3; CATALYSTS; HOMOGENEOUS PRECIPITATION; PD/ZNO CATALYST; OXIDE CATALYSTS;

D O I：

10.1016/j.apcatb.2010.06.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A large number of studies can be found in the literature regarding the production of new catalysts for methanol steam reforming. This work summarizes the latest developments on catalysts for this application and is divided in two main groups: copper-based and group 8-10 metal-based catalysts. In each section, the strategies proposed by several authors to enhance the performance of the catalysts are described. An overall comparison between the two groups shows that copper-based catalysts are the most active ones, while the 8-10 group catalysts present better results in terms of thermal stability and long-term stability. Very promising results were reported for both groups, enhancing the value of methanol as a hydrogen carrier for fuel cell applications. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：43 / 57

页数：15

共 116 条

[1] Production of hydrogen from methanol over Cu/ZnO catalysts promoted by ZrO2 and Al2O3
Agrell, J
Birgersson, H
Boutonnet, M
Melián-Cabrera, I
Navarro, RM
Fierro, JLG
[J]. JOURNAL OF CATALYSIS, 2003, 219 (02) : 389 - 403
[2] A novel method for preparing high surface area copper zirconia catalysts Influence of the preparation variables
Aguila, Gonzalo
Jimenez, Javier
Guerrero, Sichem
Gracia, Francisco
Chornik, Boris
Quinteros, Sergio
Araya, Paulo
[J]. APPLIED CATALYSIS A-GENERAL, 2009, 360 (01) : 98 - 105
[3] Hydrogen from hydrocarbon fuels for fuel cells
Ahmed, S
Krumpelt, M
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2001, 26 (04) : 291 - 301
[4] HYDROGEN-PRODUCTION BY THE CATALYTIC STEAM REFORMING OF METHANOL .2. KINETICS OF METHANOL DECOMPOSITION USING GIRDLER G66B CATALYST
AMPHLETT, JC
EVANS, MJ
MANN, RF
WEIR, RD
[J]. CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1985, 63 (04) : 605 - 611
[5] KINETICS OF CATALYTIC CONVERSION OF METHANOL AT HIGHER PRESSURES
BARTON, J
POUR, V
[J]. COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1980, 45 (12) : 3402 - 3407
[6] Hydrogen production by methanol steam reforming carried out in membrane reactor on Cu/Zn/Mg-based catalyst
Basile, A.
Parmaliana, A.
Tosti, S.
Iulianelli, A.
Gallucci, F.
Espro, C.
Spooren, J.
[J]. CATALYSIS TODAY, 2008, 137 (01) : 17 - 22
[7] Hydrogen from methanol steam-reforming over Cu-based catalysts with and without Pd promotion
Bichon, P.
Asheim, A.
Jordal, A.
Sperle, T.
Fathi, M.
Holmen, A.
Blekkan, E. A.
[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2007, 32 (12) : 1799 - 1805
[8] Methanol reforming for fuel-cell applications: development of zirconia-containing Cu-Zn-Al catalysts
Breen, JP
Ross, JRH
[J]. CATALYSIS TODAY, 1999, 51 (3-4) : 521 - 533
[9] Technology up date and new strategies on fuel cells
Cacciola, G
Antonucci, V
Freni, S
[J]. JOURNAL OF POWER SOURCES, 2001, 100 (1-2) : 67 - 79
[10] Methanol-steam reforming over a ZnO-Cr2O3/CeO2-ZrO2/Al2O3 catalyst
Cao, Weiqiang
Chen, Guangwen
Li, Shulian
Yuan, Quan
[J]. CHEMICAL ENGINEERING JOURNAL, 2006, 119 (2-3) : 93 - 98

← 1 2 3 4 5 6 7 8 9 10 →