Synthesis and Structure of Bis- and Tris-Benzyl Bismuth Complexes

被引：9

作者：

Kindra, Douglas R. ^{[1
]}

Peterson, Jeffrey K. ^{[1
]}

Ziller, Joseph W. ^{[1
]}

Evans, William J. ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

ORGANOMETALLICS | 2015年 / 34卷 / 01期

关键词：

RAY CRYSTAL-STRUCTURE; OXYARYL DIANION; CARBON; DERIVATIVES; ACTIVATION; REACTIVITY; INSERTION; GEOMETRY; ANTIMONY; LIGAND;

D O I：

10.1021/om5010786

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first crystallographic characterization of bismuth complexes containing benzyl ligands is reported. The NCN pincer ligand complex, Ar'BiCl2 [Ar' = 2,6-(Me2NCH2)(2)C6H3], reacts with (PhCH2)MgCl to form Ar'Bi(eta(1)-CH2Ph)(2) in high yield. X-ray crystallography and spectroscopic studies confirm eta(1)-bonding of the benzyl ligands in Ar'Bi(eta(1)-CH2Ph)(2) as well as in the homoleptic Bi(eta(1)-CH2Ph)(3).

引用

页码：395 / 397

页数：3

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