Thiosulfonates as Emerging Reactants: Synthesis and Applications

被引：153

作者：

Mampuys, P. ^{[1
]}

McElroy, C. R. ^{[2
]}

Clark, J. H. ^{[2
]}

Orru, R. V. A. ^{[3
,4
]}

Maes, B. U. W. ^{[1
]}

机构：

[1] Univ Antwerp, Dept Chem, Organ Synth, Groenenborgerlaan 171, B-2020 Antwerp, Belgium

[2] Univ York, Green Chem Ctr Excellence, York YO10 5DD, N Yorkshire, England

[3] Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, De Boelelaan 1108, NL-1081 HZ Amsterdam, Netherlands

[4] Vrije Univ Amsterdam, AIMMS, De Boelelaan 1108, NL-1081 HZ Amsterdam, Netherlands

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2020年 / 362卷 / 01期

关键词：

green chemistry; multicomponent reactions; sulfur; synthetic applications; thiosulfonates; S BOND FORMATION; ONE-POT REACTION; CATALYZED C-S; IMPREGNATED CHARCOAL N2O4/CHARCOAL; PEROXY ACID OXIDATION; METAL-FREE; SULFONYL HYDRAZIDES; FACILE SYNTHESIS; ALPHA-DISULFOXIDE; UNSYMMETRICAL DISULFIDES;

D O I：

10.1002/adsc.201900864

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The synthetic strategies towards thiosulfonates (RSO2SR1) are comprehensively reviewed from their original discovery to recent advances. Incorporation of the green credentials of the synthetic procedures towards thiosulfonates allows one to judge the merits of the state of the art, beyond the typical yield of a product and availability of the reactants. As reactant for organic transformations, thiosulfonates are particularly interesting given their possibility to react with nucleophiles, electrophiles and radicals. This review aims to give researchers, not familiar with the field, a good understanding of the general applications of thiosulfonates, while not skipping the recent important advances. The related, but less explored, selenosulfonates (RSO2SeR1) are also covered.

引用

页码：3 / 64

页数：62

共 369 条

[1] Use of Onion Extract as a Dairy Cattle Feed Supplement: Monitoring Propyl Propane Thiosulfonate as a Marker of Its Effect on Milk Attributes [J].