Disambiguation of Metal and Bronsted Acid Catalyzed Pathways for Hydroarylation with Platinum(II) Catalysts

被引：28

作者：

Bowring, Miriam A.

Bergman, Robert G. ^{[1
]}

Tilley, T. Don

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

ORGANOMETALLICS | 2011年 / 30卷 / 06期

关键词：

AROMATIC-SUBSTITUTION; TRIFLIC ACID; COMPLEXES; HYDROAMINATION; ACTIVATION; OLEFINS; BENZENE; ALKANES;

D O I：

10.1021/om2000458

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydroarylation of unactivated olefins effected by Pt(II) precatalysts was found to proceed through the in situ production of protic acid followed by a Friedel Crafts mechanism. The reaction was investigated using the hindered base 2,6-di-tert-butyl-4-methylpyridine and a variety of substrates.

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页码：1295 / 1298

页数：4

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