Zwitterionic side chain-modified conjugated polymers with greatly enhanced ambipolar charge-transport mobilities

被引:3
|
作者
Liu, Li-Na [1 ,2 ]
Khlil, Maria [1 ]
Li, Jia [3 ]
Xu, Zi-Wen [1 ]
Xie, Guanghui [2 ]
Li, Jingjing [2 ]
Gao, Xike [1 ]
Li, Hongxiang [1 ]
Yao, Jianhua [2 ,3 ]
Li, Wei-Shi [1 ,2 ]
机构
[1] Chinese Acad Sci, Univ Chinese Acad Sci, Ctr Excellence Mol Synth, Shanghai Inst Organ Chem,Key Lab Synthet & Self A, 345 Lingling Rd, Shanghai 200032, Peoples R China
[2] Zhengzhou Inst Technol, Engn Res Ctr Zhengzhou High Performance Organ Fun, 6 Yingcai St, Zhengzhou 450044, Henan, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Energy Regulat Mat, 345 Lingling Rd, Shanghai 200032, Peoples R China
基金
中国国家自然科学基金;
关键词
ORGANIC SEMICONDUCTORS; POLYELECTROLYTES; HOLE;
D O I
10.1039/d1cc04617a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A small amount of the 3-(hexyldimethylammonio)propane-1-sulfonate zwitterionic side chain was integrated into a diketopyrrolopyrrole ambipolar polymer to modulate its field-effect carrier-transport characteristics. It was found that such a modification can strengthen the interchain interaction, promote crystallization, and thus improve the hole and electron mobilities by 3.9- and 8.2-fold, respectively.
引用
收藏
页码:11181 / 11184
页数:4
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