[Cp*Rh(bpy)(H2O)]2+ as a coenzyme substitute in enzymatic oxidations catalyzed by Baeyer-Villiger monooxygenases

被引：40

作者：

de Gonzalo, G

Ottolina, G

Carrea, G

Fraaije, MW

机构：

[1] CNR, Ist Chim Riconoscimento Mol, I-20131 Milan, Italy

[2] Univ Groningen, Biochem Lab, Groningen Biomol Sci & Biotechnol Inst, NL-9747 AG Groningen, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 29期

关键词：

D O I：

10.1039/b504921k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Cp*Rh(bpy)(H2O)](2+) was applied as a flavin regenerating reagent in BVMO catalyzed oxidations of organic sulfides to chiral sulfoxides.

引用

页码：3724 / 3726

页数：3

共 28 条

[1] Towards large-scale synthetic applications of Baeyer-Villiger monooxygenases [J].

Alphand, V ;

Carrea, G ;

Wohlgemuth, R ;

Furstoss, R ;

Woodley, JM .

TRENDS IN BIOTECHNOLOGY, 2003, 21 (07) :318-323

[2] Enzyme-mediated catalytic asymmetric oxidations [J].

Colonna, S ;

Del Sordo, S ;

Gaggero, N ;

Carrea, G ;

Pasta, P .

HETEROATOM CHEMISTRY, 2002, 13 (05) :467-473

[3] Enantioselective oxidation of sulfides to sulfoxides catalysed by bacterial cyclohexanone monooxygenases [J].

Colonna, S ;

Gaggero, N ;

Pasta, P ;

Ottolina, G .

CHEMICAL COMMUNICATIONS, 1996, (20) :2303-2307

[4] Large scale production of cyclohexanone monooxygenase from Escherichia coli TOP10 pQR239 [J].

Doig, SD ;

O'Sullivan, LM ;

Patel, S ;

Ward, JM ;

Woodley, JM .

ENZYME AND MICROBIAL TECHNOLOGY, 2001, 28 (2-3) :265-274

[5] PURIFICATION AND PROPERTIES OF CYCLOHEXANONE OXYGENASE FROM NOCARDIA-GLOBERULA CL1 AND ACINETOBACTER NCIB-9871 [J].

DONOGHUE, NA ;

NORRIS, DB ;

TRUDGILL, PW .

EUROPEAN JOURNAL OF BIOCHEMISTRY, 1976, 63 (01) :175-192

[6] Recent developments in the synthesis and utilization of chiral sulfoxides [J].

Fernández, I ;

Khiar, N .

CHEMICAL REVIEWS, 2003, 103 (09) :3651-3705

[7] Discovery of a thermostable Baeyer-Villiger monooxygenase by genome mining [J].

Fraaije, MW ;

Wu, J ;

Heuts, DPHM ;

van Hellemond, EW ;

Spelberg, JHL ;

Janssen, DB .

APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2005, 66 (04) :393-400

[8] Identification of a Baeyer-Villiger monooxygenase sequence motif [J].

Fraaije, MW ;

Kamerbeek, NM ;

van Berkel, WJH ;

Janssen, DB .

FEBS LETTERS, 2002, 518 (1-3) :43-47

[9]

FRAAIJE MW, 2004, J BIOL CHEM, V5, P279

[10] Stereospecific biocatalytic epoxidation: The first example of direct regeneration of a FAD-dependent monooxygenase for catalysis [J].

Hollmann, F ;

Lin, PC ;

Witholt, B ;

Schmid, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (27) :8209-8217

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