Mixed valence: origins and developments

被引：133

作者：

Day, Peter ^{[1
]}

Hush, Noel S. ^{[2
]}

Clark, Robin J. H. ^{[3
]}

机构：

[1] Royal Inst Great Britain, Davy Faraday Res Lab, London W1S 4BS, England

[2] Univ Sydney, Sch Chem, Mol Elect Grp, Sydney, NSW 2006, Australia

[3] UCL, Christopher Ingold Labs, London WC1H 0AJ, England

来源：

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2008年 / 366卷 / 1862期

关键词：

mixed valence compounds; classification; structure; spectroscopy;

D O I：

10.1098/rsta.2007.2135

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Mixed-valence compounds were recognized by chemists more than a century ago for their unusual colours and stoichiometries, but it was just 40 years ago that two seminal articles brought together the then available evidence. These articles laid the foundations for understanding the physical properties of such compounds and how the latter correlate with molecular and crystal structures. This introduction to a, discussion meeting briefly surveys the history of mixed valence and sets in context contributions to the discussion describing current work in the field.

引用

页码：5 / 14

页数：10

共 66 条

[1]

Allen G.C., 1967, PROGR INORG CHEM, V8, P357, DOI DOI 10.1002/9780470166093.CH6

[2] ABSENCE OF DIFFUSION IN CERTAIN RANDOM LATTICES [J].

ANDERSON, PW .

PHYSICAL REVIEW, 1958, 109 (05) :1492-1505

[3] VIBRATIONAL SPECTRA OF SOME CHLORO-ANIONS [J].

BARROWCLIFFE, T ;

BEATTIE, IR ;

DAY, P ;

LIVINGSTON, K .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (11) :1810-+

[4] ELECTRON DELOCALIZATION IN MIXED-VALENCE MU-PYRAZINE-DECAAMMINEDIRUTHENIUM(5+) ION [J].

BEATTIE, JK ;

HUSH, NS ;

TAYLOR, PR .

INORGANIC CHEMISTRY, 1976, 15 (04) :992-993

[5] IDENTIFICATION BY RAMAN MICROSCOPY AND VISIBLE REFLECTANCE SPECTROSCOPY OF PIGMENTS ON AN ICELANDIC MANUSCRIPT [J].

BEST, SP ;

CLARK, RJH ;

DANIELS, MAM ;

PORTER, CA ;

WITHNALL, R .

STUDIES IN CONSERVATION, 1995, 40 (01) :31-40

[6] THE NEAR-INFRARED AND MID-INFRARED SPECTRUM OF THE CREUTZ-TAUBE ION IN AQUEOUS-SOLUTION - AN APPLICATION OF FTIR SPECTROELECTROCHEMICAL TECHNIQUES [J].

BEST, SP ;

CLARK, RJH ;

MCQUEEN, RCS ;

JOSS, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (02) :548-550

[7]

Burns R. G., 1970, MINERALOGICAL APPL C

[8] Oxalate-bridged complexes of dimolybdenum and ditungsten supported by pivalate ligands:: (tBuCO2)3M2(μ-O2CCO2)M2(O2CtBu)3.: Correlation of the solid-state, molecular, and electronic structures with Raman, resonance Raman, and electronic spectral data [J].

Bursten, BE ;

Chisholm, MH ;

Clark, RJH ;

Firth, S ;

Hadad, CM ;

MacIntosh, AM ;

Wilson, PJ ;

Woodward, PM ;

Zaleski, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (12) :3050-3063

[9] Calculation of electronic coupling matrix elements for ground and excited state electron transfer reactions: Comparison of the generalized Mulliken-Hush and block diagonalization methods [J].

Cave, RJ ;

Newton, MD .

JOURNAL OF CHEMICAL PHYSICS, 1997, 106 (22) :9213-9226

[10] Mixed valence complexes involving MM quadruple bonds (M=Mo or W) [J].

Chisholm, Malcolm H. .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2008, 366 (1862) :101-112

← 1 2 3 4 5 6 7 →