Speedy photocatalytic degradation of bromophenol dye over ZnO nanoflowers

被引:26
作者
Ameen, Sadia [1 ]
Akhtar, M. Shaheer [2 ]
Shin, Hyung Shik [1 ]
机构
[1] Chonbuk Natl Univ, Sch Chem Engn, Solar Energy Res Ctr, Energy Mat & Surface Sci Lab, Jeonju 54896, South Korea
[2] Chonbuk Natl Univ, New & Renewable Energy Mat Dev Ctr NewREC, Jeonju, South Korea
关键词
ZnO; Surfaces; Bromophenol dye; Nanocrystalline materials; Pollutant; Mass spectroscopy; GRAIN-BOUNDARIES; DOPED ZNO; NANOSTRUCTURES; SOLUBILITY; NANOPARTICLES; INCREASE; TIO2;
D O I
10.1016/j.matlet.2017.07.117
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A simple, low temperature solution method was employed to synthesize ZnO nanoflowers (NFs) using zinc nitrate as precursor for the photocatalytic degradation of bromophenol (Bph) dye. The synthesized materials exhibited well-defined flower like morphology comprised of several defined nanorods. The crystalline and optical observations manifested the high crystallinity of ZnO-NFs with wide band gap of similar to 3.21 eV. The synthesized ZnO NFs as catalysts presented a rapid degradation of Bph-dye with the degradation rate of similar to 96% within 120 min under the UV light irradiation. The fragmentations of Bph-dye after the photocatalytic reaction over ZnO-NFs were analyzed by interpreting the mass spectroscopy of degraded Bph-dye. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:150 / 154
页数:5
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