Visible-Light-Driven Reductive Carboarylation of Styrenes with CO2 and Aryl Halides

被引：238

作者：

Wang, Hao ^{[1
,2
]}

Gao, Yuzhen ^{[1
]}

Zhou, Chunlin ^{[1
,2
]}

Li, Gang ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Ctr Excellence Mol Synth, Fujian Inst Res Struct Matter,State Key Lab Struc, Key Lab Coal Ethylene Glycol & Its Related Techno, Fuzhou 350002, Fujian, Peoples R China

[2] Univ Chinese Acad Sci, Fujian Coll, Beijing 100049, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2020年 / 142卷 / 18期

关键词：

PHOTOINDUCED ELECTRON-TRANSFER; METAL-CATALYZED CARBOXYLATION; C-H FUNCTIONALIZATION; CARBON-DIOXIDE; PHOTOREDOX CATALYSIS; PHOTOCATALYTIC ARYLATION; UNACTIVATED ALKYL; DIAZONIUM SALTS; ALKENES; HYDROCARBOXYLATION;

D O I：

10.1021/jacs.0c03144

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first example of visible-light-driven reductive carboarylation of styrenes with CO2 and aryl halides in a regioselective manner has been achieved. A broad range of aryl iodides and bromides were compatible with this reaction. Moreover, pyridyl halides, alkyl halides, and even aryl chlorides were also viable with this method. These findings may stimulate the exploration of novel visible-light-driven Meerwein arylation-addition reactions with user-friendly aryl halides as the radical sources and the photocatalytic utilization of CO2.

引用

页码：8122 / 8129

页数：8

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