Sulfur-functionalized mesoporous carbon

被引:251
作者
Shin, Yongsoon [1 ]
Fryxell, Glen E. [1 ]
Um, Wooyong [1 ]
Parker, Kent [1 ]
Mattigod, Shas V. [1 ]
Skaggs, Richard [1 ]
机构
[1] Pacific NW Natl Lab, Richland, WA 99352 USA
关键词
D O I
10.1002/adfm.200601230
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple synthesis route to mesoporous carbons that contain heteroaromatic functionality is described. The sulfur-functionalized mesoporous carbon (S-FMC) materials that have been prepared show excellent thermal stability, as well as excellent hydrothermal stability, and stability over a wide range of pH values. These materials also show excellent mercury sorption performance over a broad range of pH, much broader than is possible with thiol-based functionality or most silica-based sorbents. The superior performance of these mesoporous heterocarbons as heavy-metal sorbent material is demonstrated. These materials are shown to be stable at elevated temperatures and extreme pHs, making them ideally suited as a new class of absorbent material.
引用
收藏
页码:2897 / 2901
页数:5
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