Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries

被引：325
作者：
Hy, Sunny [1 ]
Liu, Haodong [1 ]
Zhang, Minghao [1 ]
Qian, Danna [1 ]
Hwang, Bing-Joe [2 ]
Meng, Ying Shirley [1 ]
机构：
[1] Univ Calif San Diego, Dept NanoEngn, Lab Energy Storage & Convers, La Jolla, CA 92093 USA
[2] Natl Taiwan Univ Sci & Technol, Grad Inst Appl Sci & Technol, NanoElectrochem Lab, Taipei 106, Taiwan
来源：
ENERGY & ENVIRONMENTAL SCIENCE | 2016年 / 9卷 / 06期
关键词：
LI-RICH CATHODE; X-RAY-ABSORPTION; IRREVERSIBLE CAPACITY LOSS; ENHANCED ELECTROCHEMICAL PERFORMANCE; IMPROVED RATE CAPABILITY; HIGH-ENERGY-DENSITY; MOLTEN-SALT METHOD; VOLTAGE-FADE; IN-SITU; SURFACE MODIFICATION;
D O I：
10.1039/c5ee03573b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Li-excess oxide compound is one of the most promising positive electrode materials for next generation batteries exhibiting high capacities of 4300 mA h g(-1) due to the unconventional participation of the oxygen anion redox in the charge compensation mechanism. However, its synthesis has been proven to be highly sensitive to varying conditions and parameters where nanoscale phase separation may occur that affects the overall battery performance and life. In addition, several thermodynamic and kinetic drawbacks including large first cycle irreversible capacity, poor rate capability, voltage fading, and surface structural transformation need to be addressed in order to reach commercialization. This review will focus on the recent progress and performance trends over the years and provide several guidelines and design considerations based on the library of work done on this particular class of materials.
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收藏
页码：1931 / 1954
页数：24
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