Pd doped SnO2 based room temperature operable resistive sensor for the detection of ethanol vapors

被引:10
作者
Dhongade, Vipul [1 ]
Sharma, Lokesh [2 ]
Kahandal, Amol [2 ]
Aiyer, R. C. [1 ]
Rajdeo, Kishor [3 ]
Tagad, Chandrakant [2 ]
机构
[1] Savitribai Phule Pune Univ, Dept Elect Sci, Pune 411007, Maharashtra, India
[2] MIT ADT Univ, MIT Sch Bioengn Sci & Res, Pune 412201, Maharashtra, India
[3] Apcotex Ind Ltd, Ankleshwar 393135, India
关键词
Metal oxide; Tin oxide; Semiconductor; Ethanol sensor; Room temperature; GAS SENSORS; SENSING PERFORMANCE; NANOPARTICLES; SENSITIVITY;
D O I
10.1016/j.matpr.2020.12.973
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The present paper reports a highly sensitive room temperature operable ethanol vapor sensor based on the electrical properties of nanostructured Pd-doped SnO2. Pd-doped SnO2 thin films were prepared on the glass substrate (1.2 cm(2)) using single-step thermal decomposition of stannous chloride (SnCl2) and palladium chloride (PdCl2). The resultant films were characterized by Scanning Electron Microscopy (SEM), X-ray diffraction spectroscopy (XRD), and UV-Vis spectroscopy. The doping of SnO2 with Pd was found to enhance the ethanol sensing response operating at room temperature. The 5% Pd-doped SnO2 sensor showed higher ethanol-sensing performance than the 0, 1, and 3% Pd-doped SnO2 with the sensing range of 10-190 ppm. The response and recovery time at 40 ppm of ethanol gas were similar to 107 s and similar to 378 s. The effect of Pd doping on the optical, structural properties of SnO2 and its ethanol vapor sensing behavior was studied and discussed. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6437 / 6444
页数:8
相关论文
共 35 条
[1]   Hybrid nanomaterials designed for volatile organic compounds sensors: A review [J].
Andre, Rafaela S. ;
Sanfelice, Rafaela C. ;
Pavinatto, Adriana ;
Mattoso, Luiz H. C. ;
Correa, Daniel S. .
MATERIALS & DESIGN, 2018, 156 :154-166
[2]   Grain size effects on H-2 gas sensitivity of thick film resistor using SnO2 nanoparticles [J].
Ansari, SG ;
Boroojerdian, P ;
Sainkar, SR ;
Karekar, RN ;
Aiyer, RC ;
Kulkarni, SK .
THIN SOLID FILMS, 1997, 295 (1-2) :271-276
[3]   UV irradiation effects on hydrogen sensors based on SnO2 thin films fabricated by the photochemical deposition [J].
Ao, Dengbaoleer ;
Ichimura, Masaya .
SOLID-STATE ELECTRONICS, 2012, 69 :1-3
[4]   SnO2 film with bimodal distribution of nano-particles for low concentration hydrogen sensor: Effect of firing temperature on sensing properties [J].
Bamsaoud, Salim F. ;
Rane, S. B. ;
Karekar, R. N. ;
Aiyer, R. C. .
MATERIALS CHEMISTRY AND PHYSICS, 2012, 133 (2-3) :681-687
[5]   Nano particulate SnO2 based resistive films as a hydrogen and acetone vapour sensor [J].
Bamsaoud, Salim F. ;
Rane, S. B. ;
Karekar, R. N. ;
Aiyer, R. C. .
SENSORS AND ACTUATORS B-CHEMICAL, 2011, 153 (02) :382-391
[6]   Metal oxide sensor arrays for detection of explosives at sub-parts-per million concentration levels by the differential electronic nose [J].
Brudzewski, K. ;
Osowski, S. ;
Pawlowski, W. .
SENSORS AND ACTUATORS B-CHEMICAL, 2012, 161 (01) :528-533
[7]   Rapid one-step room-temperature solid-state synthesis and formation mechanism of ZnO nanorods as H2S-sensing materials [J].
Cao, Yali ;
Jia, Dianzeng ;
Wang, Ruiying ;
Luo, Jianmin .
SOLID-STATE ELECTRONICS, 2013, 82 :67-71
[8]   Current Understanding of the Fundamental Mechanisms of Doped and Loaded Semiconducting Metal-Oxide-Based Gas Sensing Materials [J].
Degler, David ;
Weimar, Udo ;
Barsan, Nicolae .
ACS SENSORS, 2019, 4 (09) :2228-2249
[9]   Quantification of Ethanol by Metal-Oxide-Based Resistive Sensors: A Review [J].
Dharmalingam, G. ;
Sivasubramaniam, R. ;
Parthiban, S. .
JOURNAL OF ELECTRONIC MATERIALS, 2020, 49 (05) :3009-3024
[10]   Overview of Automotive Sensors [J].
Fleming, William J. .
IEEE SENSORS JOURNAL, 2001, 1 (04) :296-308