Kinetics and mechanism of oxidation of valeraldehyde by quinolinium dichromate

被引:0
作者
Chaubey, GS [1 ]
Mahanti, MK [1 ]
机构
[1] NE Hill Univ, Dept Chem, Shillong 793003, Meghalaya, India
来源
OXIDATION COMMUNICATIONS | 2000年 / 23卷 / 04期
关键词
kinetics; oxidation; n-valeraldehyde; quinolinium dichromate;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The oxidation of n-valeraldeyde to n-valeric acid by quinolinium dichromate proceeds smoothly in aqueous acidic medium. A kinetic isotope effect of 5.80 showed that the cleavage of the carbon-hydrogen bond was the rate-determining step of the reaction.
引用
收藏
页码:500 / 504
页数:5
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