Bismuth Film Combined with Screen-Printed Electrode as Biosensing Platform for Phenol Detection

被引:24
作者
Merkoci, Arben [1 ,2 ]
Anik, Ulku [3 ]
Cevik, Serdar [3 ]
Cubukcu, Meliha [3 ,4 ]
Guix, Maria [1 ,5 ]
机构
[1] ICN, Nanobioelect & Biosensors Grp, Barcelona, Catalonia, Spain
[2] ICREA, Barcelona, Spain
[3] Mugla Univ, Fac Arts & Sci, Dept Chem, TR-48000 Kotekli Mugla, Turkey
[4] Ege Univ, Dept Chem, Fac Sci, TR-35100 Izmir, Turkey
[5] Univ Autonoma Barcelona, Dept Chem, Bellaterra 08193, Catalonia, Spain
关键词
Bi-film; Mushroom tissue; Phenol biosensor; Screen printed electrode; Biosensors; Bismuth; ANODIC-STRIPPING VOLTAMMETRY; CARBON ELECTRODES; TYROSINASE BIOSENSOR; AMPEROMETRIC PHENOL; PSEUDOMONAS-PUTIDA; TRACE-METALS; SENSOR; NANOPARTICLES; BEHAVIOR; PHASE;
D O I
10.1002/elan.200970002
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Mushroom tissue was immobilized onto plain screen printed electrode (SPE) and multiwalled carbon nanotube (MWCNT) modified SPE (SPE/MWCNT) via bismuth (Bi) deposition. By this way. SPE/Bi/Tissue and SPE/MWCNT/Bi/Tissue biosensors for phenol detection were obtained. UV-visible spectroscopy and SEM were utilized for explain the immobilization procedure. After optimizing working parameters, both biosensors were compared in terms of analytical characteristics. Linear range of response were found as 5-100 mu M for SPE/Bi/Tissue and 2- 200 mu M for SPE/MWCNT/Bi/Tissue while detection limits were calculated as 0.48 mu M and 1.1.7 mu M for SPE/Bi/ Tissue and SPE/MWCNT/Bi/Tissue respectively. Developed systems were also applied for phenol detection in synthetically prepared waste water sample and very promising results were obtained.
引用
收藏
页码:1429 / 1436
页数:8
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