Immobilization of Cyphos Ionic Liquids in Alginate Capsules for Cd(II) Sorption

被引：35

作者：

Guibal, E. ^{[1
]}

Figuerola Pinol, A. ^{[1
,2
]}

Ruiz, M. ^{[2
]}

Vincent, T. ^{[1
]}

Jouannin, C. ^{[1
]}

Sastre, A. M. ^{[3
]}

机构：

[1] Ecole Mines Ales France, Lab Genie Environm Ind, Ales, France

[2] Univ Politecn Cataluna, Dept Chem Engn, EUPVG, La Geltru, Spain

[3] Univ Politecn Cataluna, Dept Chem Engn, ETSEIB, Barcelona, Spain

来源：

SEPARATION SCIENCE AND TECHNOLOGY | 2010年 / 45卷 / 12-13期

关键词：

cadmium; desorption; diffusion; immobilization; isotherms; sorption; tetraalkylphosphonium ionic liquids; SOLVENT-IMPREGNATED RESINS; NI-CD BATTERIES; SPENT NICKEL-CADMIUM; HYDROMETALLURGICAL RECOVERY; BIOPOLYMER CAPSULES; ELECTRODE MATERIALS; MACROPOROUS RESINS; PHOSPHORIC-ACID; METAL SORPTION; LEACH LIQUORS;

D O I：

10.1080/01496395.2010.493113

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four phosphonium ionic liquids (Cyphos IL-101, IL-105, IL-109, and IL-111) have been immobilized in composite biopolymer capsules (alginate/gelatin). The resins were tested for Cd(II) sorption in HCl solutions. Cyphos IL-111 being solid at room temperature, the phase change contributes to the formation of large vesicles in the resin particle. Sorption isotherms were not affected by the anionic counterpart (chloride, dicyanamide, or tetrafluoroborate), except with bistriflamide (Cd(II) was not sorbed). HCl concentration (0.1-4.6M) did not influence the Cd(II) uptake (60mg Cd g-1). Kinetic profiles were modeled using the intraparticle diffusion equation. Highly porous foams have been developed as an alternative to resin beads in order to improve diffusion characteristics.

引用

页码：1935 / 1949

页数：15

共 60 条

[1] SOLVENT-EXTRACTION OF CADMIUM(II) FROM ACIDIC MEDIA BY CYANEX-302
ALMELA, A
ELIZALDE, MP
[J]. HYDROMETALLURGY, 1995, 37 (01) : 47 - 57
[2] HYDROMETALLURGICAL RECOVERY PROCESS FOR NICKEL-CADMIUM SPENT BATTERIES
BARTOLOZZI, M
BRACCINI, G
BONVINI, S
MARCONI, PF
[J]. JOURNAL OF POWER SOURCES, 1995, 55 (02) : 247 - 250
[3] Removal of cadmium (II) from aqueous solution using pure smectite and Lewatite S 100: the effect of time and metal concentration
Bedoui, K.
Bekri-Abbes, I.
Srasra, E.
[J]. DESALINATION, 2008, 223 (1-3) : 269 - 273
[4] Kinetic studies on cadmium ions by Amberlite XAD7 impregnated resins containing di(2-ethylhexyl) phosphoric acid as extractant
Benamor, M.
Bouariche, Z.
Belaid, T.
Draa, M. T.
[J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2008, 59 (01) : 74 - 84
[5] Brooks C.S., 1991, Metal Recovery from Industrial Waste
[6] Campbell A, 2008, BJU INT, V101, P14
[7] Gold recovery from HCl solutions using Cyphos IL-101 (a quaternary phosphonium ionic liquid) immobilized in biopolymer capsules
Campos, K.
Vincent, T.
Bunio, P.
Trochimczuk, A.
Guibal, E.
[J]. SOLVENT EXTRACTION AND ION EXCHANGE, 2008, 26 (05) : 570 - 601
[8] CIEZYNSKA A, 2007, POL J CHEM TECH, V9, P99, DOI DOI 10.2478/V10026-007-0037-4
[9] Extraction, isolation and cadmium binding of alginate from Sargassum spp.
Davis, TA
Ramirez-Dominguez, M
Mucci, A
Larsen, B
[J]. JOURNAL OF APPLIED PHYCOLOGY, 2004, 16 (04) : 275 - 284
[10] Metal selectivity of Sargassum spp. and their alginates in relation to their α-L-guluronic acid content and conformation
Davis, TA
Llanes, F
Volesky, B
Mucci, A
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2003, 37 (02) : 261 - 267

← 1 2 3 4 5 6 →